Metals at the surface of last scatter
Yacine Ali-Ha\"imoud, Christopher M. Hirata, Marc Kamionkowski

TL;DR
This paper investigates whether primordial metals could influence CMB observations and if current or upcoming measurements can constrain their abundance, concluding that Planck data won't improve existing limits on primordial metallicity.
Contribution
The study analyzes the impact of primordial metals on CMB recombination and shows that Planck's measurements are unlikely to tighten existing metallicity constraints.
Findings
Primordial metals affect CMB via three mechanisms.
Detectable effects require metal abundance above a few hundredths to tenths of solar.
Planck cannot improve constraints beyond current Lyman-alpha forest and halo star limits.
Abstract
Standard big-bang nucleosynthesis (BBN) predicts only a trace abundance of lithium and no heavier elements, but some alternatives predict a nonzero primordial metallicity. Here we explore whether CMB measurements may set useful constraints to the primordial metallicity and/or whether the standard CMB calculations are robust, within the tolerance of forthcoming CMB maps, to the possibility of primordial metals. Metals would affect the recombination history (and thus CMB power spectra) in three ways: (1) Lyman-alpha photons can be removed (and recombination thus accelerated) by photoionizing metals. (2) The Bowen resonance-fluorescence mechanism may degrade Lyman-beta photons and thus enhance the Lyman-beta escape probability and speed up recombination. (3) Metals could affect the low-redshift tail of the CMB visibility function by providing additional free electrons. The last two of…
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