Template assisted self-assembly of individual and clusters of magnetic nanoparticles

TL;DR

This paper introduces a novel template-assisted self-assembly method for magnetic nanoparticles, enabling controlled arrangement and clustering on nanostructured templates for potential applications in data storage and sensing.

Contribution

The study presents a new approach using nanostructured aluminum templates to precisely control the spatial organization of magnetic nanoparticles and their clusters.

Findings

Nanostructured templates enable controlled nanoparticle placement.

Clusters of various configurations, including chains and islands, are achieved.

Magnetic interactions within clusters are characterized using memory effects.

Abstract

The deliberate control over the spatial arrangement of nanostructures is the desired goal for many applications as e.g. in data storage, plasmonics or sensor arrays. Here we present a novel method to assist the self-assembly process of magnetic nanoparticles. The method makes use of nanostructured aluminum templates obtained after anodization of aluminum disks and the subsequent growth and removal of the newly formed alumina layer, resulting in a regular honeycomb type array of hexagonally shaped valleys. The iron oxide nanoparticles, 20 nm in diameter, are spin coated onto the nanostructured templates. Depending on the size, each hexagon site can host up to 30 nanoparticles. These nanoparticles form clusters of different arrangements within the valleys, such as collars, chains, and hexagonally closed islands. Ultimately, it is possible to isolate individual nanoparticles. The strengths of magnetic interaction between particles in a cluster is probed using the memory effect known from the coupled state in superspin glass systems.