Discovery of interstellar anions in Cepheus star-forming region
M. A. Cordiner, S. B. Charnley, J. V. Buckle, C. Walsh, T. J., Millar

TL;DR
This paper reports the first detection of interstellar anions and long-chain molecules in the Cepheus star-forming region, expanding understanding of complex chemistry in star-forming environments and highlighting the widespread presence of anions in dense interstellar clouds.
Contribution
It presents the first detection of interstellar anions and long-chain polyynes in Cepheus, demonstrating their significance in star formation chemistry outside Taurus.
Findings
Detection of C6H- and C6H in Cepheus star-forming region.
Anion-to-neutral ratios of about 4%, consistent across different clouds.
Rotational temperatures of 6.2 K and 8.7 K in the observed regions.
Abstract
We report the detection of microwave emission lines from the hydrocarbon anion C6H- and its parent neutral C6H in the star-forming region L1251A (in Cepheus), and the pre-stellar core L1512 (in Auriga). The carbon-chain-bearing species C4H, HC3N, HC5N, HC7N and C3S are also detected in large abundances. The observations of L1251A constitute the first detections of anions and long-chain polyynes and cyanopolyynes (with more than 5 carbon atoms) in the Cepheus Flare star-forming region, and the first detection of anions in the vicinity of a protostar outside of the Taurus molecular cloud complex, highlighting a wider importance for anions in the chemistry of star formation. Rotational excitation temperatures have been derived from the HC3N hyperfine structure lines, and are found to be 6.2 K for L1251A and 8.7 K for L1512. The anion-to-neutral ratios are 3.6% and 4.1%, respectively, which…
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