Theory of Elastic Interaction of the Colloidal Particles in the Nematic Liquid Crystal Near One Wall and in the Nematic Cell

TL;DR

This paper develops a theoretical framework for elastic interactions of colloidal particles in nematic liquid crystals near walls and in confined cells, predicting new interaction behaviors and matching experimental data.

Contribution

The paper extends existing models to include wall effects and predicts novel interaction phenomena in confined nematic liquid crystals.

Findings

Effective power of dipole-dipole repulsion varies with distance and height.

Attraction zones are significantly altered near planar walls.

The theory aligns well with experimental observations for sphere interactions.

Abstract

We apply the method developed in Ref. [S.B.Chernyshuk and B.I.Lev, Phys.Rev.E, \textbf{81}, 041701 (2010)] for theoretical investigation of colloidal elastic interactions between axially symmetric particles in the confined nematic liquid crystal (NLC) near one wall and in the nematic cell with thickness $L$. Both cases of homeotropic and planar director orientations are considered. Particularly dipole-dipole, dipole-quadrupole and quadrupole-quadrupole interactions of the \textit{one} particle with the wall and within the nematic cell are found as well as corresponding \textit{two particle} elastic interactions. A set of new results has been predicted: the effective power of repulsion between two dipole particles at height $h$ near the homeotropic wall is reduced gradually from inverse 3 to 5 with an increase of dimensionless distance $r/h$; near the planar wall - the effect of dipole-dipole \textit{isotropic attraction} is predicted for large distances $r>r_{dd}=4.76 h$; maps of attraction and repulsion zones are crucially changed for all interactions near the planar wall and in the planar cell; one dipole particle in the homeotropic nematic cell was found to be shifted by the distance $\delta_{eq}$ from the center of the cell \textit{independent} of the thickness $L$ of the cell. The proposed theory fits very well with experimental data for the confinement effect of elastic interaction between spheres in the homeotropic cell taken from [M.Vilfan et al. Phys.Rev.Lett. {\bf 101}, 237801, (2008)] in the range $1\div1000 kT$.