Exact partition function zeros and the collapse transition of a two-dimensional lattice polymer

TL;DR

This paper investigates the collapse transition of a two-dimensional lattice polymer by calculating exact partition function zeros, providing insights into the transition temperature and critical behavior through finite-size scaling analysis.

Contribution

It introduces a method to compute exact partition function zeros for lattice polymers and analyzes their distribution to identify the collapse transition.

Findings

Zeros approach the real axis as chain length increases

Estimated transition temperature for the collapse transition

Determined crossover exponent from zero scaling behavior

Abstract

We study the collapse transition of the lattice homopolymer on a square lattice by calculating the exact partition function zeros. The exact partition function is obtained by enumerating the number of possible conformations for each energy value, and the exact distributions of the partition function zeros are found in the complex temperature plane by solving a polynomial equation. We observe that the locus of zeros closes in on the positive real axis as the chain length increases, providing the evidence for the onset of the collapse transition. By analyzing the scaling behavior of the first zero with the polymer length, we estimate the transition temperature and the crossover exponent.