An extended infrared study of the (p,T) phase diagram of the p-doped Cu-O plane

TL;DR

This study uses infrared spectroscopy to map the (p,T) phase diagram of the Cu-O plane in various cuprates, revealing the insulator-metal transition, mid-infrared features, and Fermi liquid behavior in the superconducting phase.

Contribution

It provides a detailed infrared characterization of the doping and temperature dependence of the phase diagram in cuprates, including the insulator-metal transition and optical properties in the superconducting state.

Findings

Observation of a bound state at 1570 cm-1 at very low doping

Identification of a softening FIR band leading to the insulator-metal transition

Infrared spectral weight consistent with a Fermi liquid with strong correlations

Abstract

The ab-plane optical conductivity of eleven single crystals, belonging to the families Sr2-xCuO2Cl2, Y1-xCaxBa2Cu3O6, Bi2Sr2-xLaxCuO6, and Bi2Sr2CaCu2O8 has been measured with hole concentrations p between 0 and 0.18, and for 6 K < T < 500 K to obtain an infrared picture of the p,T phase diagram of the Cu-O plane. At extreme dilution (p = 0.005), a narrow peak is observed at 1570 cm-1 (195 meV), that we assign to a single-hole bound state. For increasing doping, that peak broadens into a far-infrared (FIR) band whose low-energy edge sets the insulating gap. The insulator-to-metal transition (IMT) occurs when the softening of the FIR band closes the gap thus evolving into a Drude term. In the metallic phase, a multi-band analysis identifies a mid-infrared band which weakly depends on temperature and softens for increasing p, while the extended-Drude analysis leads to an optical scattering rate larger than the frequency, as found in other cuprates. The infrared spectral weight W(T) is consistent with a Fermi liquid renormalized by strong correlations, provided that the T^4 term of the Sommerfeld expansion is included above 300 K. In the superconducting phase, the optical response of single-layer Bi2Sr2-xLaxCuO6 at optimum doping is similar to that of the corresponding optimally-doped bilayer Bi2Sr2CaCu2O8.