Near constant loss dielectric response in 2Bi2O3-B2O3 glasses

TL;DR

This study investigates the dielectric response of 2Bi2O3-B2O3 glasses, revealing near constant loss behavior at high frequencies and temperatures, with implications for ionic conduction and relaxation mechanisms.

Contribution

It provides new insights into the dielectric properties and conduction mechanisms of bismuth borate glasses, highlighting near constant loss behavior and ion hopping phenomena.

Findings

Near constant loss response observed between 1 kHz and 1 MHz.

Thermal activation energy for ion hopping is approximately 0.48 eV.

High dielectric constant and low loss suggest potential for dielectric applications.

Abstract

Electrical conduction and relaxation phenomena in bismuth borate glasses in the composition 2Bi2O3-B2O3 (Bi4B2O9) were investigated. Dielectric studies carried out on these glasses revealed near constant loss (NCL) response in the 1 kHz to 1MHz frequency range at moderately high temperatures (300-450K) associated with relatively low loss (D=0.006) and high dielectric constant ({\epsilon}r'=37) at 1kHz,300K. The variation in AC conductivity with temperature at different frequencies showed a cross over from NCL response characterized by local ion vibration within the potential well to universal Joncher's power law dependence triggered by ion hopping between potential wells or cages. Thermal activation energy for single potential well was found to be 0.48 \pm 0.05eV from cross over points. Ionic conduction and relaxation processes were rationalized by modulus formalism. The promising dielectric properties (relatively high {\epsilon}r' and low D) of the present glasses were attributed to high density (93 % of its crystalline counterpart), high polarizability and low mobility associated with heavy metal cations, Bi3+.