From nanoparticles to nanocrystalline bulk: Field assisted sintering of silicon nanoparticles

TL;DR

This study demonstrates how field-assisted sintering of silicon nanoparticles can produce nanocrystalline bulk materials with controlled microstructure by analyzing current pathways and heat profiles during the process.

Contribution

It provides new insights into the microstructural evolution during field-assisted sintering, combining experimental and theoretical approaches to optimize nanocrystalline silicon bulk production.

Findings

Nanocrystalline silicon bulk can be achieved with controlled microstructure.

Current pathways influence microstructure development during sintering.

Density fluctuations are linked to heat profiles in powder networks.

Abstract

Nanocrystalline bulk materials are desirable for many applications as they combine mechanical strength and specific electronic transport properties. Our bottom up approach starts with tailored nanoparticles. Compaction and thermal treatment are crucial, but usually the final stage sintering is accompanied by rapid grain growth which spoils nanocristallinity. For electrically conducting nanoparticles, field activated sintering techniques overcome this problem. Small grain sizes have been maintained in spite of consolidation. Nevertheless, the underlying principles, which are of high practical impact, have not been fully elucidated yet. In this combined experimental and theoretical work we show, how the developing microstructure during sintering correlates to the percolation paths of the current through the powder using highly doped silicon nanoparticles as a model system. It is possible to achieve a nanocrystalline bulk material and a homogeneous microstructure. For this, not only the generation of current paths due compaction, but also the disintegration due to joule heating is required. The observed density fluctuations on the micrometer scale are attributed to the specific heat profile of the simulated powder networks.