Mechanical control of vibrational states in single-molecule junctions

TL;DR

This study demonstrates that the conductance of single-molecule junctions can be mechanically controlled by altering molecular conformation and contact material, providing insights into charge transport at the molecular level.

Contribution

It introduces a method to manipulate single-molecule conductance through mechanical adjustments of molecular conformation and contact material.

Findings

Conductance depends on contact material and configuration.

Molecular conformation influences charge transport.

Mechanical control enables tuning of single-molecule conductance.

Abstract

We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation between the molecular conformation and conduction properties of a single-molecule junction. We demonstrate that the conductance through single molecules crucially depends on the contact material and configuration by virtue of their mechanical and electrical properties. Our findings prove that the charge transport via single molecules can be manipulated by varying both the molecular conformation (e.g., trans or gauche) and the contact material.