Magnetic structure and spin dynamics of quasi-one-dimensional spin-chain antiferromagnet BaCo2V2O8

TL;DR

This study investigates the magnetic structure and spin dynamics of BaCo2V2O8, revealing a complex antiferromagnetic order and critical slowing down of spin fluctuations near the transition temperature.

Contribution

It provides a detailed model of the magnetic structure and spin dynamics of BaCo2V2O8 using neutron diffraction and muSR, highlighting temperature-dependent magnetic behavior.

Findings

Antiferromagnetic structure with moments aligned along c-axis

Spin fluctuations slow down near the transition temperature

Magnetic order follows the 3D Ising model

Abstract

We report a neutron diffraction and muon spin relaxation muSR study of static and dynamical magnetic properties of BaCo2V2O8, a quasi-one-dimensional spin-chain system. A proposed model for the antiferromagnetic structure includes: a propagation vector k_AF = (0, 0, 1), independent of external magnetic fields for fields below a critical value H_c(T). The ordered moments, of 2.18 \mu_B per Co ion, are aligned along the crystallographic c-axis. Within the screw chains, along the c axis, the moments are arranged antiferromagnetically. In the basal planes the spins are arranged ferromagnetically (forming zig-zags paths) along one of the axis and antiferromagnetically along the other. The temperature dependence of the sub-lattice magnetization is consistent with the expectations of the 3D Ising model. A similar behavior is observed for the internal static fields at different muon stopping sites. Muon time spectra measured at weak longitudinal fields and temperatures much higher than T_N can be well described using a single muon site with an exponential muon spin relaxation that gradually changes into an stretched exponential on approaching T_N. The temperature-induced changes of the relaxation suggest that the Co fluctuations dramatically slow down and the system becomes less homogeneous as it approaches the antiferromagnetic state.