Diffusion of a fluid through a viscoelastic solid

TL;DR

This paper develops a thermodynamic model for fluid diffusion through viscoelastic solids under large deformations, aligning well with experimental data and exploring swelling behavior.

Contribution

It introduces a novel thermodynamic framework for modeling fluid diffusion in viscoelastic solids, incorporating large deformation effects and constitutive relations.

Findings

Model agrees with experimental solvent diffusion data

Derived relations for stresses and interaction forces

Analyzed swelling under external forces

Abstract

This paper is concerned with the diffusion of a fluid through a viscoelastic solid undergoing large deformations. Using ideas from the classical theory of mixtures and a thermodynamic framework based on the notion of maximization of the rate of entropy production, the constitutive relations for a mixture of a viscoelastic solid and a fluid (specifically Newtonian fluid) are derived. By prescribing forms for the specific Helmholtz potential and the rate of dissipation, we derive the relations for the partial stress in the solid, the partial stress in the fluid, the interaction force between the solid and the fluid, and the evolution equation of the natural configuration of the solid. We also use the assumption that the volume of the mixture is equal to the sum of the volumes of the two constituents in their natural state as a constraint. Results from the developed model are shown to be in good agreement with the experimental data for the diffusion of various solvents through high temperature polyimides that are used in the aircraft industry. The swelling of a viscoelastic solid under the application of an external force is also studied.