Statistical properties of entropy production derived from fluctuation theorems

TL;DR

This paper explores the statistical properties of entropy production using fluctuation theorems, deriving bounds on variance and probability, and introducing new inequalities that extend the second law.

Contribution

It introduces improved bounds on entropy production variance and probability, and presents a general method for deriving inequalities beyond the second law.

Findings

Lower bound on variance of entropy production derived

Tighter bounds on probability of negative entropy production

New inequalities for entropy production beyond the second law

Abstract

Several implications of well-known fluctuation theorems, on the statistical properties of the entropy production, are studied using various approaches. We begin by deriving a tight lower bound on the variance of the entropy production for a given mean of this random variable. It is shown that the Evans-Searles fluctuation theorem alone imposes a significant lower bound on the variance only when the mean entropy production is very small. It is then nonetheless demonstrated that upon incorporating additional information concerning the entropy production, this lower bound can be significantly improved, so as to capture extensivity properties. Another important aspect of the fluctuation properties of the entropy production is the relationship between the mean and the variance, on the one hand, and the probability of the event where the entropy production is negative, on the other hand. Accordingly, we derive upper and lower bounds on this probability in terms of the mean and the variance. These bounds are tighter than previous bounds that can be found in the literature. Moreover, they are tight in the sense that there exist probability distributions, satisfying the Evans-Searles fluctuation theorem, that achieve them with equality. Finally, we present a general method for generating a wide class of inequalities that must be satisfied by the entropy production. We use this method to derive several new inequalities which go beyond the standard derivation of the second law.