Photoinduced Phase Transitions

TL;DR

This paper discusses how ultrafast, photon-induced electronic excitations can trigger various phase transitions, emphasizing their non-equilibrium nature and potential for controlling material states on femtosecond timescales.

Contribution

It provides a unified perspective on photoinduced phase transitions, highlighting their mechanisms, control laws, and potential applications in non-equilibrium physics.

Findings

Photoinduced transitions occur on a few hundred femtoseconds.

Electronic excitations alter cohesive energy and chemical potential.

Photon effects can both weaken and strengthen atomic bonds.

Abstract

Optically induced ultrafast electronic excitations with sufficiently long lifetimes may cause strong effects on phase transitions like structural and nonmetal to metal ones. Examples are transitions diamond to graphite, graphite to graphene, non-metal to metal, solid to liquid and vapor to liquid, solid. A spectacular case is photo-induced water condensation. These non-equilibrium transitions are an ultrafast response, on a few hundred fs-time scale, to the fast electronic excitations. The energy of the photons is converted into electronic one via electronic excitations changing the cohesive energy. This changes the chemical potential controlling the phase transition. In view of the advances in laser optics photon induced transitions are expected to become an active area in non-equilibrium physics and phase transition dynamics. Conservation laws like energy or angular momentum conservation control the time during which the transitions occur. Since the photon induced effects result largely from weakening or strenghtening of the bonding between the atoms or molecules transitions like solid/liquid etc. can be shifted in both directions. Photoinduced transitions will be discussed from an unified point of view.