Storage of Quantum Coherences as Phase Labeled Local Polarization in Solid State NMR

TL;DR

This paper demonstrates how quantum coherences in solid state NMR can be stored as local polarization using field gradients, effectively freezing and later recovering them, which has implications for quantum memory applications.

Contribution

It introduces a method to control the freezing and recovery of quantum coherences in solid state NMR via field gradients, highlighting the role of inhomogeneities.

Findings

Coherences can be stored as local polarization and recovered after long times.

Field gradients enable controlled freezing and retrieval of quantum states.

Inhomogeneities significantly influence multipulse sequence outcomes.

Abstract

Nuclear spins are promising candidates for quantum information processing because their good isolation from the environment precludes the rapid loss of quantum coherence. Many strategies have been developed to further extend their decoherence times. Some of them make use of decoupling techniques based on the Carr-Purcell and Carr-Purcell-Meiboom-Gill pulse sequences. In many cases, when applied to inhomogeneous samples, they yield a magnetization decay much slower than the Hahn echo. However, we have proved that these decays cannot be associated with longer decoherence times as coherences remain frozen. They result from coherences recovered after their storage as local polarization and thus they can be used as memories. We show here how this freezing of the coherent state, which can subsequently be recovered after times longer than the natural decoherence time of the system, can be generated in a controlled way with the use of field gradients. A similar behaviour of homogeneous samples in inhomogeneous fields are demonstrated. It is emphasized that the effects of inhomogeneities in solid state NMR, independently of their origin, should not be disregarded as they play a crucial role in multipulse sequences.