Nonharmonic oscillations of nanosized cantilevers due to quantum-size effects
Martin Olsen, Per Gradin, Ulf Lindefelt, H{\aa}kan Olin

TL;DR
This paper predicts that quantum-size effects cause nanoscale cantilevers to exhibit nonharmonic oscillations with amplitude-dependent resonance frequencies, due to changes in electron states affecting the spring constant.
Contribution
It introduces a model linking quantum electron states to mechanical oscillations, revealing oscillatory behavior in the spring constant of nanowire cantilevers.
Findings
Spring constant oscillates with bending due to quantum effects
Resonance frequency depends on oscillation amplitude
Quantum-size effects are detectable in nanoscale mechanical systems
Abstract
Using a one-dimensional jellium model and standard beam theory we calculate the spring constant of a vibrating nanowire cantilever. By using the asymptotic energy eigenvalues of the standing electron waves over the nanometer-sized cross-section area, the change in the grand canonical potential is calculated and hence the force and the spring constant. As the wire is bent more electron states fits in its cross section. This has an impact on the spring"constant" which oscillates slightly with the bending of the wire. In this way we obtain an amplitude-dependent resonance frequency of the oscillations that should be detectable.
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