Observation of re-entrant spin glass behavior in (Ce1-xErx)Fe2 compounds

TL;DR

This study provides experimental evidence of re-entrant spin glass behavior in Er-doped CeFe2 compounds, highlighting the role of Er substitution and valence changes in inducing a spin glass state distinct from magnetic glass.

Contribution

It demonstrates the presence of re-entrant spin glass behavior in (Ce1-xErx)Fe2 compounds through comprehensive experimental analysis, clarifying the nature of the low-temperature magnetic state.

Findings

Re-entrant spin glass state confirmed by bifurcation and frequency dependence.

Spin glass behavior linked to Er substitution and valence changes.

Low temperature state is not a magnetic glass, no exchange bias observed.

Abstract

Clear experimental evidence of re-entrant spin glass state has been revealed in Er doped CeFe2 compounds. The zero field cooled - field cooled bifurcation in dc magnetization, frequency dependence of freezing temperature, relaxation in zero field cooled magnetization and presence of large remanence confirm the spin glass state in these compounds. Frequency dependence is found to follow the critical slowing down mechanism. The random substitution of Er and the change in the valence state of Ce along with an enhancement of the ferromagnetic component in the Fe sublattice seem to be responsible for the spin glass state. Using detailed experimental protocols, we also prove that the low temperature state in these compounds is not a magnetic glass. The absence of exchange bias gives an indication that there is no coexistence of ferromagnetism and spin glass state in these compounds. The RSG state is found to be associated with the randomly magnetized clusters instead of atomic level randomness.