Dielectric properties of Li2O-3B2O3 glasses

TL;DR

This study investigates the dielectric and electrical properties of Li2O-3B2O3 glasses across various frequencies and temperatures, revealing ion hopping mechanisms and phase transformation to LiB3O5 upon heating.

Contribution

It provides a detailed analysis of dielectric relaxation and conductivity mechanisms in Li2O-3B2O3 glasses, highlighting ion transport and phase change behavior.

Findings

Activation energy for dc conductivity is 0.80 eV.

Electrical relaxation involves ion hopping mechanisms.

Heating induces phase transformation to LiB3O5.

Abstract

The frequency and temperature dependence of the dielectric constant and the electrical conductivity of the transparent glasses in the composition Li2O-3B2O3 (LBO) were investigated in the 100 Hz- 10 MHz frequency range. The dielectric constant and the loss in the low frequency regime were electrode material dependent. Dielectric and electrical relaxations were respectively analyzed using the Cole-Cole and electric modulus formalisms. The dielectric relaxation mechanism was discussed in the framework of electrode and charge carrier (hopping of the ions) related polarization using generalized Cole-Cole expression. The frequency dependent electrical conductivity was rationalized using Jonscher's power law. The activation energy associated with the dc conductivity was 0.80 \pm 0.02 eV, which was ascribed to the motion of Li+ ions in the glass matrix. The activation energy associated with dielectric relaxation was almost equal to that of the dc conductivity, indicating that the same species took part in both the processes. Temperature dependent behavior of the frequency exponent (n) suggested that the correlated barrier hopping model was the most apposite to rationalize the electrical transport phenomenon in Li2O-3B2O3 glasses. These glasses on heating at 933 K/10h resulted in the known non-linear optical phase LiB3O5.