Ad- and desorption of Rb atoms on a gold nanofilm measured by surface plasmon polaritons

TL;DR

This study uses surface plasmon polaritons to measure real-time adsorption and desorption of Rubidium atoms on gold nanofilms, providing detailed insights into atom-surface interactions crucial for quantum sensor development.

Contribution

It introduces a phase-sensitive method to quantify Rb atom coverage on gold nanofilms and compares experimental data with a Langmuir model to determine desorption rates and sticking probabilities.

Findings

Rubidium coverage can be measured with better than 0.3% sensitivity of a monolayer.

Thermal desorption rate and sticking probability are quantified.

Laser-induced desorption is observed and characterized.

Abstract

Hybrid quantum systems made of cold atoms near nanostructured surfaces are expected to open up new opportunities for the construction of quantum sensors and for quantum information. For the design of such tailored quantum systems the interaction of alkali atoms with dielectric and metallic surfaces is crucial and required to be understood in detail. Here, we present real-time measurements of the adsorption and desorption of Rubidium atoms on gold nanofilms. Surface plasmon polaritons (SPP) are excited at the gold surface and detected in a phase sensitive way. From the temporal change of the SPP phase the Rubidium coverage of the gold film is deduced with a sensitivity of better than 0.3 % of a monolayer. By comparing the experimental data with a Langmuir type adsorption model we obtain the thermal desorption rate and the sticking probability. In addition, also laser-induced desorption is observed and quantified.