Vapor Pressure of Ionic Liquids
Markus Bier, S. Dietrich
TL;DR
This paper explains that the very low vapor pressures of room temperature ionic liquids near their triple points are caused by their strong ionic nature combined with low melting temperatures.
Contribution
It provides a theoretical explanation linking ionic character and melting points to vapor pressure in ionic liquids.
Findings
Vapor pressures are extremely low near triple points.
Strong ionic character reduces vapor pressure.
Low melting temperatures contribute to vapor pressure behavior.
Abstract
We argue that the extremely low vapor pressures of room temperature ionic liquids near their triple points are due to the combination of strong ionic characters and of low melting temperatures.
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