$c$-axis charge gap and its critical point in the heavily doped Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$

TL;DR

This study investigates the doping-dependent evolution of the c-axis charge gap in Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ using resistivity and magnetic measurements, revealing a critical doping point where the charge gap vanishes and metallic behavior emerges.

Contribution

It identifies a doping level where the charge gap closes and correlates this with magnetic and transport properties, providing new insights into the phase diagram of iron-based superconductors.

Findings

Charge gap temperature $T_{CG}$ vanishes near doping $x_{CG} \,\approx\, 0.30$.

A characteristic temperature $T^*$ decreases with doping and disappears near $x^* \approx 0.25$.

Inter-plane resistivity correlates with NMR Knight shift, indicating pseudo-gap formation.

Abstract

Temperature-dependent inter-plane resistivity, $\rho _c(T)$, was used to characterise the normal state of the iron-arsenide superconductor Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ over a broad doping range $0\leq x<0.50$. The data were compared with in-plane resistivity, $\rho _a(T)$, and magnetic susceptibility, $\chi (T)$, taken in $H \bot c$, as well as Co NMR Knight shift, $^{59}K$, and spin relaxation rate, $1/T_1T$. The inter-plane resistivity data show a clear correlation with the NMR Knight shift, assigned to the formation of the pseudo-gap. Evolution of $\rho _c(T)$ with doping reveals two characteristic energy scales. The temperature of the cross-over from non-metallic, increasing on cooling, behavior of $\rho _c(T)$ at high-temperatures to metallic behavior at low temperatures, $T^*$, correlates well with an anomaly in all three magnetic measurements. This characteristic temperature, equal to approximately 200~K in the parent compound, $x$=0, decreases with doping and vanishes near $x^* \approx$0.25. For doping levels $x \geq 0.166$, an additional feature appears above $T^*$, with metallic behavior of $\rho _c (T)$ found above the low-temperature resistivity increase. The characteristic temperature of this charge-gap formation, $T_{\rm CG}$, vanishes at $x_{\rm CG} \simeq$0.30, paving the way to metallic, $T$-linear, $\rho_c (T)$ close to $x_{\rm CG}$ and super-linear $T$-dependence for $x>x_{\rm CG}$. None of these features are evident in the in-plane resistivity $\rho_a(T)$. For doping levels $x <x_{\rm CG}$, $\chi (T)$ shows a known, anomalous, $T$-linear dependence, which disappears for $x>x_{\rm CG}$.