Structural, Magnetic and Electron Transport Properties of Ordered-Disordered Perovskite Cobaltites

TL;DR

This paper reviews the structural, magnetic, and electron transport properties of ordered-disordered perovskite cobaltites, focusing on La-Ba-Co-O phases, their phase transitions, and underlying mechanisms like Zener double exchange.

Contribution

It provides a comprehensive analysis of La-Ba-Co-O cobaltites, highlighting their magnetic and transport behaviors and discussing the limitations of existing models.

Findings

La-Ba-Co-O cobaltites exhibit ferromagnetic transition at ~177K.

Ordered-disordered structures influence electron transport and magnetic properties.

Discussion of hopping models and Zener double exchange mechanism.

Abstract

Rare earth perovskite cobaltites are increasingly recognized as materials of importance due to rich physics and chemistry in their ordered-disordered structure for the same composition. Apart from colossal magnetoresistance effect, like manganites, the different forms of cobaltites exhibit interesting phenomena including spin, charge and orbital ordering, electronic phase separation, insulator-metal transition, large thermoelectric power at low temperature. Moreover, the cobaltites which display colossal magnetoresistance effect could be used as read heads in magnetic data storage and also in other applications depending upon their particular properties. The A-site ordereddisordered cobaltites exhibit ferromagnetism and metal-insulator transitions as well as other properties depending on the composition, size of A-site cations and various external factors such as pressure, temperature, magnetic field etc. Ordered cobaltites, having a 112-type layered structure, are also reported to have an effectively stronger electron coupling due to layered A-site cationic ordering. Most importantly for the present article we focus on La-Ba-Co-O based ordered-disordered perovskite phases, which exhibit interesting magnetic and electron transport properties with ferromagnetic transition, TC ~ 177K, and it being the first member of lanthanide series. Zener double exchange mechanism considered to be crucial for understanding basic physics of the ferromagneticmetallic phase, yet does not explain clearly the insulating-type phase. In terms of electron transport the ferromagnetic-metallic or insulating/semiconducting states have been discussed in the present article with different types of hopping model.