Valence band and core-level analysis of highly luminescent ZnO nanocrystals for designing ultrafast optical sensors

TL;DR

This study synthesizes highly luminescent ZnO:Na nanocrystals, analyzes their electronic structure via XPS, and demonstrates their potential for ultrafast optical sensors due to quantum confinement effects.

Contribution

The paper introduces a novel synthesis method for ZnO:Na nanocrystals and provides detailed surface and electronic structure analysis relevant for optical sensor design.

Findings

Band gap increased from 3.30 eV (bulk) to 4.16 eV (nano)

Surface Na+ ions confirmed by XPS analysis

Nanocrystals exhibit ultrafast photoluminescence response

Abstract

Highly luminescent ZnO:Na nanocrystals of size ~2 nm were synthesized using a improved sol-lyophilization process. The surface analysis such as survey scan, core-level and valence band spectra of ZnO:Na nanocrystals were studied using x-ray photoelectron spectroscopy (XPS) to establish the presence of Na+ ions. The observed increase in band gap from 3.30 (bulk) to 4.16 eV (nano), is attributed to the quantum confinement of the motion of electron and holes in all three directions. The photoluminescence and decay measurements have complemented and supported our study to design an efficient and ultrafast responsive optical sensing device.