Electric field suppression of ultracold confined chemical rates

TL;DR

This paper investigates how electric fields influence ultracold polar molecule collisions in optical lattices, revealing that electric fields can suppress chemical quenching rates and potentially enable efficient cooling.

Contribution

It introduces a quantum scattering framework to analyze electric field effects on ultracold molecular collisions, demonstrating suppression of quenching rates with applied electric fields.

Findings

Electric fields suppress chemical quenching rates in ultracold polar molecules.

Predicted molecular lifetimes of about 1 second under realistic conditions.

Elastic to quenching collision rate ratio of approximately 100.

Abstract

We consider ultracold collisions of polar molecules confined in a one dimensional optical lattice. Using a quantum scattering formalism and a frame transformation method, we calculate elastic and chemical quenching rate constants for fermionic molecules. Taking KRb molecules as a prototype, we find that the rate of quenching collisions is enhanced at zero electric field as the confinement is increased, but that this rate is suppressed when the electric field is turned on. For molecules with 500 nK of collision energy, for realistic molecular densities, and for achievable experimental electric fields and trap confinements, we predict lifetimes of KRb molecules of 1 s. We find a ratio of elastic to quenching collision rates of about 100, which may be sufficient to achieve efficient experimental evaporative cooling of polar KRb molecules.