Pressure effects on the magnetic structure in La0.5Ca0.5-xSrxMnO3 (0.1 -< x -< 0.4) manganites

TL;DR

This study investigates how high pressure influences the magnetic structures of La0.5Ca0.5-xSrxMnO3 manganites, revealing pressure-induced phase coexistence, suppression of certain magnetic phases, and the fragility of CE-type antiferromagnetism.

Contribution

It demonstrates the pressure-dependent evolution of magnetic phases in La0.5Ca0.5-xSrxMnO3 and highlights the role of disorder and ionic radii in magnetic stability.

Findings

Pressure induces coexistence of magnetic phases at certain compositions.

CE-type antiferromagnetic phase is suppressed by pressure as Sr doping increases.

Magnetic moments decrease with pressure, indicating phase destabilization.

Abstract

The effect of high pressure (0 - 8 GPa) on the magnetic structure of polycrystalline samples of La0.5Ca0.5-xSrxMnO3 (0.1 -< x -< 0.4) manganites at 5 K is investigated using neutron diffraction technique. Application of pressure is found to modify the previously reported magnetic structure, observed under ambient conditions, in these compounds [I. Dhiman et al., Phys. Rev. B 77, 094440 (2008)]. In x = 0.1 composition, at 4.6(2) GPa and beyond, A-type antiferromagnetic structure is found to coexist with CE-type antiferromagnetic phase, observed at ambient pressure, with TN ~ 150 K. For x = 0.3 sample, as a function of pressure the CE-type phase is fully suppressed at 2.3(1) GPa and A-type antiferromagnetic phase is favored. Further Sr doping at x = 0.4, the A-type antiferromagnetic phase is observed at ambient pressure and for T < TN (~ 250K). This phase is retained in the studied pressure range. However, the magnetic moment progressively reduces with increasing pressure, indicating the suppression of A-type antiferromagnetic phase. The present study brings out the fragile nature of the CE-type antiferromagnetic state in half doped manganites as a function of pressure and disorder \sigma 2. We observe that pressure required for destabilizing the CE-type antiferromagnetic state is reduced with increasing disorder \sigma 2. External pressure and changing A-site ionic radii have analogous effect on the magnetic structure.