Effects of Mismatch Strain and Substrate Surface Corrugation on Morphology of Supported Monolayer Graphene

TL;DR

This paper theoretically investigates how mismatch strain and substrate surface corrugation influence the morphology and stability of supported graphene monolayers, revealing conditions for corrugation formation and potential control methods.

Contribution

It provides a theoretical framework predicting morphological stability, critical strains, and the effects of substrate surface features on supported graphene morphology.

Findings

Critical compressive strain induces graphene corrugation.

Substrate surface corrugation affects graphene morphology and stability.

Tensile strain reduces corrugation amplitude, while surface patterning can control morphology.

Abstract

Graphene monolayers supported on oxide substrates have been demonstrated with superior charge mobility and thermal transport for potential device applications. Morphological corrugation can strongly influence the transport properties of the supported graphene. In this paper, we theoretically analyze the morphological stability of a graphene monolayer on an oxide substrate, subject to van der Waals interactions and in-plane mismatch strains. First, we define the equilibrium separation and the interfacial adhesion energy as the two key parameters that characterize the van der Waals interaction between a flat monolayer and a flat substrate surface. By a perturbation analysis, a critical compressive mismatch strain is predicted, beyond which the graphene monolayer undergoes strain-induced instability, forming corrugations with increasing amplitude and decreasing wavelength on a perfectly flat surface. When the substrate surface is not perfectly flat, the morphology of graphene depends on both the amplitude and the wavelength of the surface corrugation. A transition from conformal (corrugated) to non-conformal (flat) morphology is predicted. The effects of substrate surface corrugation on the equilibrium mean thickness of the supported graphene and the interfacial adhesion energy are analyzed. Furthermore, by considering both the substrate surface corrugation and the mismatch strain, it is found that, while a tensile mismatch strain reduces the corrugation amplitude of graphene, a corrugated substrate surface promotes strain-induced instability under a compressive strain. These theoretical results suggest possible means to control the morphology of graphene monolayer on oxide substrates by surface patterning and strain engineering.