Uniaxial strain detwinning of CaFe2As2 and BaFe2As2: optical and transport study

TL;DR

This study demonstrates a reversible mechanical detwinning method for CaFe2As2 and BaFe2As2, revealing intrinsic in-plane anisotropic properties through optical and transport measurements, and compares their resistivity anisotropy below and above the structural transition.

Contribution

It introduces a nearly complete, reversible detwinning technique for these compounds, enabling direct measurement of anisotropic properties and revealing differences in their behavior above the transition temperature.

Findings

Resistivity decreases along the orthorhombic a_o-axis.

Resistivity increases along the orthorhombic b_o-axis.

BaFe2As2 shows anisotropy in the tetragonal phase, unlike CaFe2As2.

Abstract

TThe parent compounds of iron-arsenide superconductors, $A$Fe$_{2}$As$_{2}$ ($A$=Ca, Sr, Ba), undergo a tetragonal to orthorhombic structural transition at a temperature $T_{\mathrm{TO}}$ in the range 135 to 205K depending on the alkaline earth element. Below $T_{\mathrm{TO}}$ the free standing crystals split into equally populated structural domains, which mask intrinsic, in-plane, anisotropic properties of the materials. Here we demonstrate a way of mechanically detwinning CaFe$_{2}$As$_{2}$ and BaFe$_{2}$As$_{2}$. The detwinning is nearly complete, as demonstrated by polarized light imaging and synchrotron $X$-ray measurements, and reversible, with twin pattern restored after strain release. Electrical resistivity measurements in the twinned and detwinned states show that resistivity, $\rho$, decreases along the orthorhombic $a_{o}$-axis but increases along the orthorhombic $b_{o}$-axis in both compounds. Immediately below $T_{\mathrm{TO}}$ the ratio $\rho_{bo}/ \rho_{ao}$ = 1.2 and 1.5 for Ca and Ba compounds, respectively. Contrary to CaFe$_{2}$As$_{2}$, BaFe$_{2}$As$_{2}$ reveals an anisotropy in the nominally tetragonal phase, suggesting that either fluctuations play a larger role above $T_{\mathrm{TO}}$ in BaFe$_{2}$As$_{2}$ than in CaFe$_{2}$As$_{2}$, or that there is a higher temperature crossover or phase transition.