Synthesis of fine particles of a geometrically frustrated spin-chain system, Ca3Co2O6, through a pyrophoric route and its magnetic behavior

TL;DR

This study introduces a new pyrophoric synthesis method for Ca3Co2O6 particles, revealing how particle size influences magnetic properties and the multistep magnetization behavior in this geometrically frustrated spin-chain system.

Contribution

A novel pyrophoric synthesis route for Ca3Co2O6 particles is developed, enabling control over particle size and providing new insights into its magnetic behavior.

Findings

Particle diameter controlled by TEA fraction.

Multistep magnetic features diminish with smaller particles.

Temperature dependence of relaxation time persists at all sizes.

Abstract

We report the synthesis of fine particles of a well-known geometrically frustrated spin-chain compound Ca3Co2O6 through a new route, namely, a pyrophoric method employing triathanolamine (TEA) and studied the magnetic behavior of such specimens. We find that this synthesis yields particles made up of rods whose diameter appears to be controllable by the fraction of TEA during synthesis. It is seen that the two well-known magnetic transitions (near 24 and 8 K) remain unaffected for all TEA concentrations used. The most notable finding is that the multi-step feature in the M versus magnetic-field isotherm reported for single crystalline form tends to smoothen out gradually with decreasing rod thickness (from about 1 micron to about a few hundred nm). Further, unlike for the single crystalline form known in the literature, there is no tendency for the relaxation time (tau) to remain constant at low temperatures (<10 K) and tau remains temperature dependent up to the lowest temperature measured (1.8K) in all the specimens. These findings suggest that the multistep magnetization anomaly in this system may be characterized by a magnetic correlation length.