Single-molecule Nanomagnets

TL;DR

This paper reviews the physical properties of single-molecule nanomagnets, focusing on their quantum tunneling, magnetic avalanches, and potential for quantum computing applications.

Contribution

It provides a comprehensive overview of two prototypical nanomagnets, Mn_12-acetate and Fe_8, highlighting recent experimental advances and future research directions.

Findings

Observation of quantum tunneling in nanomagnets

Magnetic avalanches at low temperatures

Potential for quantum coherence in quantum computing

Abstract

Single molecule magnets straddle the classical and quantum mechanical worlds, displaying many fascinating phenomena. They may have important technological applications in information storage and quantum computation. We review the physical properties of two prototypical molecular nanomagnets, Mn_12-acetate and Fe_8: each behaves as a rigid, spin-10 object, and exhibits tunneling between up and down directions. As temperature is lowered, the spin reversal process evolves from thermal activation to pure quantum tunneling. At low temperatures, magnetic avalanches occur in which the magnetization of an entire sample rapidly reverses. We discuss the important role that symmetry-breaking fields play in driving tunneling and in producing Berry-phase interference. Recent experimental advances indicate that quantum coherence can be maintained on time scales sufficient to allow a meaningful number of quantum computing operations to be performed. Efforts are underway to create monolayers and to address and manipulate individual molecules.