The superconducting and magnetic states in RuSr2GdCu2O8, based on the magnetic, transport and magneto-caloric characteristics

TL;DR

This study investigates the magnetic and superconducting properties of RuSr2GdCu2O8, revealing inhomogeneous superconducting phases, magnetic dilution effects, and complex magnetic interactions, with implications for understanding its magnetic ordering and phase separation.

Contribution

The paper provides new insights into the inhomogeneous superconducting phase formation and magnetic behavior of RuSr2GdCu2O8, highlighting the effects of stoichiometry and structural modifications.

Findings

Evidence of inhomogeneous superconducting phase formation.

Magnetic dilution indicated by shift in T_m.

No significant magnetic entropy change across fields.

Abstract

The article discusses selected properties of the non- and superconducting polycrystalline samples of RuSr2GdCu2O8 and comments the consequences of introducing insignificant sub-stoichiometry of Ru into the nominal formula. The magneto-resistive and the magnetic characteristics are interpreted in favour of the formation of the intrinsically inhomogeneous superconducting phase, which seems to be stabilized along with the structural modifications likely enhanced with the modification of starting stoichiometry. The specific heat data reveals the shift of temperature of the magnetic ordering T_{m}, suggesting the dilution in magnetic sublattice of the Ru moments. The measurements of the magnetic field dependences of the isothermal magnetocaloric coefficient M_{T} show that there is no gain in magnetic entropy in a broad range of the accessed fields and temperatures. Whereas the multi-component character of the probed magnetic system precludes from concluding on the ground state for the Ru ordering, the maximum in M_{T}(H) which occurs at weak magnetic fields for temperature vicinity of T_{m} may reflect dominance of the ferromagnetic type interactions with a constrained correlation range. The literature explored models for the Ru magnetic ordering and possible phase separation in the RuSr2GdCu2O8 are brought into the discussion.