Microscopic theory of absorption and emission in nanostructured solar cells: Beyond the generalized Planck formula

TL;DR

This paper develops a microscopic quantum theory for absorption and emission in nanostructured solar cells, extending beyond the generalized Planck law, and demonstrates its application through numerical simulations of quantum well diodes.

Contribution

It introduces a comprehensive non-equilibrium Green's function approach that generalizes the Planck law for nanostructured photovoltaic systems.

Findings

Quantum confinement effects influence absorption and emission.

The extended theory accurately predicts radiative limits in quantum well diodes.

The approach provides a more general framework than traditional models.

Abstract

Absorption and emission in inorganic bipolar solar cells based on low dimensional structures exhibiting the effects of quantum confinement is investigated in the framework of a comprehensive microscopic theory of the optical and electronic degrees of freedom of the photovoltaic system. In a quantum-statistical treatment based on non-equilibrium Green's functions, the optical transition rates are related to the conservation of electronic currents, providing a quantum version of the balance equations describing the operation of a photovoltaic device. The generalized Planck law used for the determination of emission from an excited semiconductor in quasi-equilibrium is replaced by an expression of extended validity, where no assumptions on the distribution of electrons and photons are made. The theory is illustrated by the numerical simulation of single quantum well diodes at the radiative limit.