Theory of phonon-mediated relaxation in doped quantum dot molecules

TL;DR

This paper develops a non-perturbative quantum kinetic theory to analyze phonon-mediated relaxation in doped quantum dot molecules, revealing rapid relaxation dominated by off-diagonal couplings and emphasizing the importance of non-Markovian effects.

Contribution

It introduces a comprehensive microscopic theory accounting for both diagonal and off-diagonal carrier-phonon couplings in quantum dot molecules.

Findings

Relaxation occurs on a picosecond timescale.

Off-diagonal coupling significantly influences phonon-assisted tunneling.

Non-Markovian effects are crucial in current experimental regimes.

Abstract

A quantum dot molecule doped with a single electron in the presence of diagonal and off-diagonal carrier-phonon couplings is studied by means of a non-perturbative quantum kinetic theory. The interaction with acoustic phonons by deformation potential and piezoelectric coupling is taken into account. We show that the phonon-mediated relaxation is fast on a picosecond timescale and is dominated by the usually neglected off-diagonal coupling to the lattice degrees of freedom leading to phonon-assisted electron tunneling. We show that in the parameter regime of current electrical and optical experiments, the microscopic non-Markovian theory has to be employed.