Room-temperature ferromagnetism in graphite driven by 2D networks of point defects

TL;DR

This study provides direct evidence of room-temperature ferromagnetism in graphite caused by 2D networks of point defects at grain boundaries, highlighting an intrinsic magnetic behavior in carbon-based materials.

Contribution

It demonstrates that ferromagnetism in graphite arises intrinsically from defect structures, specifically grain boundary point defects, without magnetic impurities.

Findings

Ferromagnetism observed at room temperature in HOPG.

Magnetic order linked to defect structures at grain boundaries.

Localized electronic states depend on defect spacing.

Abstract

Ferromagnetism in carbon-based materials is appealing for both applications and fundamental science purposes because carbon is a light and bio-compatible material that contains only s and p electrons in contrast to traditional ferromagnets based on 3d or 4f electrons. Here we demonstrate direct evidence for ferromagnetic order locally at defect structures in highly oriented pyrolytic graphite (HOPG) with magnetic force microscopy and in bulk magnetization measurements at room temperature. Magnetic impurities have been excluded as the origin of the magnetic signal after careful analysis supporting an intrinsic magnetic behavior of carbon. The observed ferromagnetism has been attributed to originate from unpaired electron spins localized at grain boundaries of HOPG. Grain boundaries form two-dimensional arrays of point defects, where their spacing depends on the mutual orientation of two grains. Depending on the distance between these point defects, scanning tunneling spectroscopy of grain boundaries showed two intense split localized states for small distances between defects (< 4 nm) and one localized state at the Fermi level for large distances between defects (> 4 nm).