# On the room temperature multiferroic BiFeO3: Magnetic, dielectric and thermal properties

## TL;DR

This study comprehensively investigates the magnetic, dielectric, and thermal properties of single crystalline BiFeO3 at room temperature and below, revealing details about its antiferromagnetic order, magnon excitations, and ferroelectric polarization.

## Contribution

It provides new detailed measurements of BiFeO3's magnetic, dielectric, and thermal properties across a wide temperature range, including intrinsic dielectric constant and ferroelectric polarization at low temperatures.

## Key findings

- Antiferromagnetic order onset near 635 K.
- Magnon excitation gap of about 6 meV.
- Intrinsic dielectric constant of 53 at microwave frequencies.

## Abstract

Magnetic dc susceptibility between 1.5 and 800 K, ac susceptibility and magnetization, thermodynamic properties, temperature dependence of radio and audio-wave dielectric constants and conductivity, contact-free dielectric constants at mm-wavelengths, as well as ferroelectric polarization are reported for single crystalline BiFeO3. A well developed anomaly in the magnetic susceptibility signals the onset of antiferromagnetic order close to 635 K. Beside this anomaly no further indications of phase or glass transitions are indicated in the magnetic dc and ac susceptibilities down to the lowest temperatures. The heat capacity has been measured from 2 K up to room temperature and significant contributions from magnon excitations have been detected. From the low-temperature heat capacity an anisotropy gap of the magnon modes of the order of 6 meV has been determined. The dielectric constants measured in standard two-point configuration are dominated by Maxwell-Wagner like effects for temperatures T > 300 K and frequencies below 1 MHz. At lower temperatures the temperature dependence of the dielectric constant and loss reveals no anomalies outside the experimental errors, indicating neither phase transitions nor strong spin phonon coupling. The temperature dependence of the dielectric constant was measured contact free at microwave frequencies. At room temperature the dielectric constant has an intrinsic value of 53. The loss is substantial and strongly frequency dependent indicating the predominance of hopping conductivity. Finally, in small thin samples we were able to measure the ferroelectric polarization between 10 and 200 K. The saturation polarization is of the order of 40 microC/cm^2, comparable to reports in literature.

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Source: https://tomesphere.com/paper/0910.0385