Magnetic properties and spin dynamics in single molecule paramagnets Cu6Fe and Cu6Co

TL;DR

This study investigates the magnetic properties and spin dynamics of two molecular magnets, Cu6Fe and Cu6Co, revealing weak intramolecular interactions and classifying them as a new type of single molecule paramagnets.

Contribution

It provides detailed experimental analysis of magnetic interactions and spin dynamics in Cu6Fe and Cu6Co, highlighting their weak intramolecular coupling and classification as a new class of molecular magnets.

Findings

Cu6Fe exhibits weak ferromagnetic interaction (J=0.14 K).

Cu6Co shows weak antiferromagnetic interaction (J=-1.12 K).

Both behave as single molecule paramagnets with minimal intramolecular interactions.

Abstract

The magnetic properties and the spin dynamics of two molecular magnets have been investigated by magnetization and d.c. susceptibility measurements, Electron Paramagnetic Resonance (EPR) and proton Nuclear Magnetic Resonance (NMR) over a wide range of temperature (1.6-300K) at applied magnetic fields, H=0.5 and 1.5 Tesla. The two molecular magnets consist of CuII(saldmen)(H2O)}6{FeIII(CN)6}](ClO4)38H2O in short Cu6Fe and the analog compound with cobalt, Cu6Co. It is found that in Cu6Fe whose magnetic core is constituted by six Cu2+ ions and one Fe3+ ion all with s=1/2, a weak ferromagnetic interaction between Cu2+ moments through the central Fe3+ ion with J = 0.14 K is present, while in Cu6Co the Co3+ ion is diamagnetic and the weak interaction is antiferromagnetic with J = -1.12 K. The NMR spectra show the presence of non equivalent groups of protons with a measurable contact hyperfine interaction consistent with a small admixture of s-wave function with the d-function of the magnetic ion. The NMR relaxation results are explained in terms of a single ion (Cu2+, Fe3+, Co3+) uncorrelated spin dynamics with an almost temperature independent correlation time due to the weak magnetic exchange interaction. We conclude that the two molecular magnets studied here behave as single molecule paramagnets with a very weak intramolecular interaction, almost of the order of the dipolar intermolecular interaction. Thus they represent a new class of molecular magnets which differ from the single molecule magnets investigated up to now, where the intramolecular interaction is much larger than the intermolecular one.