Electric field-induced colossal electroresistance and its relaxation in multiferroic La2NiMnO6

TL;DR

This study investigates electric field-induced resistivity switching and relaxation in multiferroic La2NiMnO6, revealing abrupt resistivity changes, threshold behaviors, and the role of self-heating and intrinsic mechanisms in nonlinear electrical transport.

Contribution

It demonstrates electric field-induced colossal electroresistance and relaxation phenomena in La2NiMnO6, highlighting the roles of self-heating and intrinsic effects beyond Joule heating in resistivity switching.

Findings

Resistivity switches abruptly at a threshold electric field.

The threshold electric field increases exponentially with decreasing temperature.

Nonlinear conduction persists under pulsed voltages, indicating intrinsic mechanisms.

Abstract

In this work, we report direct as well as pulsed electric field-induced resistivity switching and its relaxation in a multiferroic insulator La2NiMnO6. At a fixed base temperature (Tb), the dc resistivity switches abruptly from a high to a low value, which is manifested as an upward jump in the dc current density (J) when the electric field (E) exceeds a threshold value Eth. The fractional change in the resistance is as much as 70 % at room temperature for Eth = 95 V/cm. The Eth increases with lowering Tb and follows the relation Eth(Tb) = Eth(0)exp[-Tb/T0], as similar to the behavior found in charge density wave systems. It is shown that the abrupt jump in J vanishes under pulsed electric fields if the period between pulses is long enough. Surprisingly, a step-like increase in J also occurs at a fixed dc electric field (Ec) and T = Tb, above a threshold waiting time (tth). The tth decreases with increasing Ec and Tb. Simultaneous measurement of surface temperature during the J-E sweep and temporal studies suggest that conductive channels are created in an insulating matrix due to the local self heating, and the coalescence of these channels above a threshold E- field or time causes the observed anomalies in J. However, the dissipated Joule power (P = Ith2R) at the transition from high to low resistive state in the sample decreases with lowering temperature, which suggests that the Joule heating is the consequence of transition from the high to low resistance state rather than itself a driving force of the non linear electrical transport. In addition, non linear J-E characteristics is also found even with a pulsed voltage sweep, which suggests that intrinsic mechanisms other than self heating is still active in this material.