Conformational transitions of polyelectrolytes in poor solvents

TL;DR

This paper models the conformational behavior of polyelectrolytes in poor solvents, analyzing how salt concentration influences their structure and phase transitions using the uniform expansion method.

Contribution

It introduces a detailed theoretical analysis of polyelectrolyte conformations, including the effects of salt on blob sizes and transition nature, using the uniform expansion method.

Findings

Electrostatic blob size increases with salt concentration.

Transition from pearl necklace to dissolved state is continuous at a critical salt level.

The critical salt concentration is linked to the Debye screening length.

Abstract

Starting with a model Hamiltonian, we study using the uniform expansion method conformational behavior of polyelectrolytes in the presence and absence of salt. The uniform expansion method yields all the important local length scales in the polyelectrolyte: the electrostatic blob size at large fraction of charges, the thermal blob size at low fraction of charges and the sizes of pearls (beads) and necklaces (strings) at intermediate fraction of charges. In the presence of salt, the electrostatic blob size depends on the ionic strength and increases with the increase in the salt concentration. We determine the salt concentration at which the pearl necklace intermediates dissolve and the nature of the transition changes from discontinuous to continuous. This critical salt concentration corresponds to the length scale where the Debye screening length is of the order of the necklace length.