Charge transfer effects, thermo- and photochromism in single crystal CVD synthetic diamond

TL;DR

This study investigates how thermal treatment and UV irradiation affect defect concentrations and optical properties in single crystal CVD synthetic diamond, revealing charge transfer processes and defect dynamics.

Contribution

It provides new insights into defect behavior and charge transfer mechanisms in CVD diamond under thermal and UV treatments, with detailed spectroscopic analysis.

Findings

Thermal treatment reduces certain absorption features and defect concentrations.

UV illumination restores defect states and optical absorption features.

Charge transfer occurs between NVH and nitrogen centers with specific activation energies.

Abstract

We report on the effects of thermal treatment and ultraviolet irradiation on the point defect concentrations and optical absorption profiles of single crystal CVD synthetic diamond. All thermal treatments were below 850 K, which is lower than the growth temperature and unlikely to result in any structural change. UV-visible absorption spectroscopy measurements showed that upon thermal treatment (823 K), various broad absorption features diminished: an absorption band at 270 nm (used to deduce neutral single substitutional nitrogen (NS 0) concentrations), and also two broad features centred at approximately 360 and 520 nm. Point defect centre concentrations as a function of temperature were also deduced using electron paramagnetic resonance (EPR) spectroscopy. Above ~500 K, we observed a decrease in the concentration of NS 0 centres and a concomitant increase in the negatively charged nitrogen-vacancy-hydrogen complex (NVH \bar) concentration. Both transitions exhibited an activation energy between 0.6 and 1.2 eV, which is lower than that for the NS 0 donor (~1.7 eV). Finally, it was found that illuminating samples with intense short-wave ultraviolet light recovered the NS 0 concentration and also the 270, 360 and 520 nm absorption features. From these results, we postulate a valence-band mediated charge-transfer process between NVH and single nitrogen centres with an acceptor trap depth for NVH of 0.6- 1.2 eV. Because the loss of NS 0 concentration is greater than the increase in NVH \bar concentration we also suggest the presence of another unknown acceptor existing at a similar energy as NVH. The extent to which the colour in CVD synthetic diamond is dependent on prior history is discussed.