Piezoresistance in chemically synthesized polypyrrole thin films

TL;DR

This study investigates the piezoresistive properties of chemically synthesized polypyrrole thin films, revealing how film thickness and gas pressure influence resistance changes, with implications for chemical sensing and pressure detection.

Contribution

It demonstrates the coexistence of chemical and piezoresistive responses in polypyrrole films and analyzes how film thickness and pressure affect the piezoresistive behavior.

Findings

Piezoresistance varies with film thickness and pressure.

Negative piezoresistance observed in films below 70 nm.

Behavior changes from negative to positive at certain pressures.

Abstract

The resistance of chemically synthesized polypyrrole (PPy) thin films is investigated as a function of the pressure of various gases as well as of the film thickness. A physical, piezoresistive response is found to coexist with a chemical response if the gas is chemically active, like, e.g., oxygen. The piezoresistance is studied separately by exposing the films to the chemically inert gases such as nitrogen and argon. We observe that the character of the piezoresistive response is a function not only of the film thickness, but also of the pressure. Films of a thickness below 70 nm show a decreasing resistance as pressure is applied, while for thicker films, the piezoresistance is positive. Moreover, in some films of thickness of about 70 nm, the piezoresistive response changes from negative to positive as the gas pressure is increased above 500 mbars. This behavior is interpreted in terms of a total piezoresistance which is composed of a surface and a bulk component, each of which contributes in a characteristic way. These results suggest that in polypyrrole, chemical sensing and piezoresistivity can coexist, which needs to be kept in mind when interpreting resistive responses of such sensors.