Sticking dynamics of deformable colloids

TL;DR

This study investigates the sticking behavior of deformable colloids using microrheology and optical tweezers, revealing a transition from viscous to elastic coupling and identifying regimes of stuck, non-stuck, and aging dynamics.

Contribution

It introduces a detailed experimental analysis of colloid sticking dynamics, highlighting the crossover from viscous to elastic coupling and the distinct regimes observed.

Findings

Identified three regimes: stuck, non-stuck, and aging.

Demonstrated a crossover from viscous to elastic coupling.

Observed non-single-relaxation behavior in aging regime.

Abstract

The sticking of a soft polystyrene colloidal particle to a planar glass plate was studied by a microrheological technique using an optical tweezer to trap the particle and a piezoelectric-stage to position the plate and to sinusoidally drive it in-planeThe sticking process was well-described by a crossover of the mechanical coupling between the plate and the particle from being dominantly viscous to becoming dominantly elastic. By varying three parameters in the experiment, namely, the strength of the tweezer potential, the strength of the particle-plate interaction and the strength of the oscillatory drive, three different regimes of dynamics - stuck, non-stuck and ageing were observed, corresponding to the coupling that is elastic, viscous and viscoelastic, respectively. The observations of [1] can be illustrated better by a parametric Nyquist plot of the real and imaginary parts of the effective rigidity modulus of the coupling medium. Upon contact between the particle and the plate, these parameters change abruptly from their bulk values, regardless of whether the particle is stuck or non-stuck in the terminal steady state. In the ageing regime, where sticking evolves gradually in time, the system shows a parametric plot significantly different from what would be expected from a single-relaxation process. A tendency of clustering of the data in the Nyquist plot provides an interesting contrast between truly many-body systems and one with a few degrees of freedom.