Negative continuum effects on the two-photon decay rates of hydrogen-like ions
A. Surzhykov (GSI), J.P. Santos (DFFCT, CFA), P. Amaro (DFFCT, CFA,, LKB - Jussieu), Paul Indelicato (LKB - Jussieu)

TL;DR
This paper investigates the impact of negative-energy states on two-photon decay rates in hydrogen-like ions using relativistic quantum theory, highlighting the importance of including these states for accurate calculations across different atomic numbers.
Contribution
It provides a detailed analysis of negative-energy state effects on two-photon decay rates, emphasizing their significance in both high and low atomic number systems.
Findings
Negative-energy states significantly affect decay rate calculations.
Proper summation over negative-energy states is essential for accuracy.
Results apply to hydrogen, xenon, and uranium ions.
Abstract
Two--photon decay of hydrogen--like ions is studied within the framework of second--order perturbation theory, based on relativistic Dirac's equation. Special attention is paid to the effects arising from the summation over the negative--energy (intermediate virtual) states that occurs in such a framework. In order to investigate the role of these states, detailed calculations have been carried out for the and transitions in neutral hydrogen H as well as for hydrogen--like xenon Xe and uranium U ions. We found that for a correct evaluation of the total and energy--differential decay rates, summation over the negative--energy part of Dirac's spectrum should be properly taken into account both for high-- and low-- atomic systems.
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