Response of Seven Crystallographic Orientations of Sapphire Crystals to Shock Stresses of 16 to 86 GPa

TL;DR

This study investigates how seven different crystallographic orientations of sapphire respond to shock stresses up to 86 GPa, focusing on shock wave profiles, elastic limits, and optical transparency to identify the best orientation for transparent windows under high pressure.

Contribution

It provides the first detailed comparison of shock responses across seven sapphire orientations, highlighting the m- and s-cut as optimal for transparency at high pressures.

Findings

m- and s-cut sapphire exhibit minimal heterogeneity and fastest plastic wave rise times.

Largest Hugoniot Elastic Limits observed along c-axis and perpendicular to c.

m- and s-cut orientations are most suitable for transparent high-pressure windows.

Abstract

Shock-wave profiles of sapphire (single-crystal Al2O3) with seven crystallographic orientations were measured with time-resolved VISAR interferometry at shock stresses in the range 16 to 86 GPa. Shock propagation was normal to the surface of each cut. The angle between the c-axis of the hexagonal crystal structure and the direction of shock propagation varied from 0 for c-cut up to 90 degrees for m-cut in the basal plane. Based on published shock-induced transparencies, shock-induced optical transparency correlates with the smoothness of the shock-wave profile. The ultimate goal was to find the direction of shock propagation in sapphire that is most transparent as a window. Particle velocity histories were recorded at the interface between a sapphire crystal and a LiF window. In most cases measured wave profiles are noisy as a result of heterogeneity of deformation. Measured values of Hugoniot Elastic Limits (HELs) depend on direction of shock compression and peak shock stress. The largest HEL values were recorded for shock loading along the c-axis and perpendicular to c along the m-direction. Shock compression along the m- and s-directions is accompanied by the smallest heterogeneity of deformation and the smallest rise time of the plastic shock wave. m- and s-cut sapphire most closely approach ideal elastic-plastic flow, which suggests that m- and s-cut sapphire are probably the orientations that remains most transparent to highest shock pressures. Under purely elastic deformation sapphire has very high spall strength, which depends on load duration and peak stress. Plastic deformation of sapphire causes loss of its tensile strength.