Experimental band structure of the nearly half-metallic CuCr$_2$Se$_4$: An optical and magneto-optical study

TL;DR

This study investigates the optical and magneto-optical properties of CuCr$_2$Se$_4$, revealing a distinct mid-infrared transition linked to its nearly half-metallic nature and high spin polarization.

Contribution

It provides detailed experimental optical and magneto-optical spectra of CuCr$_2$Se$_4$ and connects these findings with band structure calculations, highlighting a unique mid-infrared transition.

Findings

Observation of a mid-infrared optical transition at 0.5 eV with strong magneto-optical activity

Identification of the transition as a parity-allowed process through Se-Cr hybridization

High spin polarization and spin-orbit interaction explain the large off-diagonal conductivity

Abstract

Diagonal and off-diagonal optical conductivity spectra have been determined form the measured reflectivity and magneto-optical Kerr effect (MOKE) over a broad range of photon energy in the itinerant ferromagnetic phase of CuCr$_2$Se$_4$ at various temperatures down to T=10 K. Besides the low-energy metallic contribution and the lower-lying charge transfer transition at $E$$\approx$2 eV, a sharp and distinct optical transition was observed in the mid-infrared region around $E$$=$0.5 eV with huge magneto-optical activity. This excitation is attributed to a parity allowed transition through the Se-Cr hybridization-induced gap in the majority spin channel. The large off-diagonal conductivity is explained by the high spin polarization in the vicinity of the Fermi level and the strong spin-orbit interaction for the related charge carriers. The results are discussed in connection with band structure calculations.