Search for Ferromagnetism in doped semiconductors in the absence of transition metal ions

TL;DR

This paper investigates the potential for ferromagnetism in doped semiconductors without transition metal ions, using a generalized Hubbard model and numerical simulations to identify conditions for high-spin ground states.

Contribution

It introduces a generalized Hubbard model accounting for electron-hole asymmetry and disorder, demonstrating ferromagnetic ground states in doped semiconductors at nanoscale.

Findings

Ferromagnetic ground states are possible in doped semiconductors modeled by the generalized Hubbard model.

High-spin states are observed in small 2D systems with disorder and electron-hole asymmetry.

Ferromagnetism can occur in quantum dots and heterostructures, not just bulk materials.

Abstract

In contrast to semiconductors doped with transition metal magnetic elements, which become ferromagnetic at temperatures below ~ 100K, semiconductors doped with non-magnetic ions (e.g. silicon doped with phosphorous) have not shown evidence of ferromagnetism down to millikelvin temperatures. This is despite the fact that for low densities the system is expected to be well modeled by the Hubbard model, which is predicted to have a ferromagnetic ground state at T=0 on 2- or 3-dimensional bipartite lattices in the limit of strong correlation near half-filling. We examine the impurity band formed by hydrogenic centers in semiconductors at low densities, and show that it is described by a generalized Hubbard model which has, in addition to strong electron-electron interaction and disorder, an intrinsic electron-hole asymmetry. With the help of mean field methods as well as exact diagonalization of clusters around half filling, we can establish the existence of a ferromagnetic ground state, at least on the nanoscale, which is more robust than that found in the standard Hubbard model. This ferromagnetism is most clearly seen in a regime inaccessible to bulk systems, but attainable in quantum dots and 2D heterostructures. We present extensive numerical results for small systems that demonstrate the occurrence of high-spin ground states in both periodic and positionally disordered 2D systems. We consider how properties of real doped semiconductors, such as positional disorder and electron-hole asymmetry, affect the ground state spin of small 2D systems. We also discuss the relationship between this work and diluted magnetic semiconductors, such as Ga_(1-x)Mn_(x)As, which though disordered, show ferromagnetism at relatively high temperatures.