Effective Time Reversal Symmetry Breaking and Energy Spectra of Graphene Armchair Rings
Tianhuan Luo, A.P. Iyengar, H.A. Fertig, L. Brey

TL;DR
This paper investigates the energy spectra of graphene armchair rings, revealing signatures of effective broken time reversal symmetry (EBTRS) through phase shifts and spectral gaps, and explores effects of geometry deviations.
Contribution
It demonstrates how corner junctions induce phase shifts mimicking flux tubes, leading to EBTRS signatures in graphene rings, including spectral gaps and broken particle-hole symmetry.
Findings
Spectral gap around zero energy due to EBTRS
Application of magnetic flux can close the spectral gap
Non-particle-hole symmetric spectra in five and seven sided rings
Abstract
We study the energy spectra and wavefunctions of graphene rings formed from metallic armchair ribbons, near zero energy, to search for properties which may be identified with "effective broken time reversal symmetry" (EBTRS). Appropriately chosen corner junctions are shown to impose phase shifts in the wavefunctions that at low energies have the same effect as effective flux tubes passing near the ribbon surface. Closing the ribbon into a ring captures this flux and yields properties that may be understood as signatures of EBTRS. These include a gap in the spectrum around zero energy, which can be removed by the application of real magnetic flux through the ring. Spectra of five and seven sided rings are also examined, and it is shown these do not have particle-hole symmetry, which may also be understood as a consequence of EBTRS, and is connected to the curvature induced in the system…
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