Particle size effect on magnetic properties of interacting La0.67Sr0.33MnO3 nanoparticles

TL;DR

This study investigates how particle size influences the magnetic properties of La0.67Sr0.33MnO3 nanoparticles, revealing size-dependent magnetic dynamics and evidence of superspin glass behavior through detailed susceptibility analysis.

Contribution

It provides a comprehensive analysis of magnetic relaxation and interactions in LSMO nanoparticles of various sizes using Vogel-Fulcher and critical slowing down laws.

Findings

Presence of strong magnetic interactions between nanoparticles

Size-dependent magnetic relaxation behavior

Evidence of superspin glass state in nanoparticles

Abstract

Magnetic nanoparticles of La0.67Sr0.33MnO3 (LSMO) manganite with mean particle sizes of 13, 16, 18 and 21 nm were prepared by the sol-gel method. The crystal structure and mean particle size of the synthesized powders were estimated by X-ray diffraction (XRD) analysis using rietveld refinement and transmission electron microscopy (TEM). Fourier transform infrared (FTIR) transmission spectroscopy revealed that stretching and bending modes are influenced by calcinations temperature. Dc magnetization versus magnetic field of the samples was carried out at room temperature. Magnetic dynamics of the samples was studied by the measurement of ac magnetic susceptibility versus temperature at different frequencies and ac magnetic fields. A frequency-dependent peak was observed in ac magnetic susceptibility versus temperature which is well described by Vogel-Fulcher and critical slowing down laws, and empirical and parameters. By fitting the experimental data with Vogel-Fulcher and critical slowing down laws, the relaxation time, characteristic temperature, magnetic anisotropy energy, effective magnetic anisotropy constant and critical exponent zv have been estimated. The obtained values of c1, c2, T0 and t0 from the Vogel-Fulcher law support of the presence of strong interaction between magnetic nanoparticles. The values of zv and t0 obtained from critical slowing down fit suggest the presence of superspin glass behavior in LSMO nanoparticles of different sizes.