Determination of the magnetic structure of Yb3Pt4: a k=0 local-moment antiferromagnet

TL;DR

This study used neutron diffraction to determine the magnetic structure of Yb3Pt4, revealing a k=0 antiferromagnetic order with localized Yb moments and a complex interplay of anisotropies influencing the magnetic orientation.

Contribution

The paper provides the first detailed neutron diffraction analysis of Yb3Pt4's magnetic structure, identifying a specific antiferromagnetic arrangement and clarifying the role of anisotropies in moment orientation.

Findings

Yb3Pt4 exhibits a k=0 antiferromagnetic structure.

Ordered Yb moments are approximately 0.81 μB at 1.4 K.

The magnetic moments are localized and influenced by crystal-electric field and anisotropic exchange.

Abstract

We have used neutron diffraction measurements to study the zero-field magnetic structure of the intermetallic compound Yb3Pt4, which was earlier found to order antiferromagnetically at the Neel temperature TN=2.4 K, and displays a field-driven quantum critical point at 1.6 T. In Yb3Pt4, the Yb moments sit on a single low-symmetry site in the rhombohedral lattice with space group R-3. The Yb ions form octahedra with edges that are twisted with respect to the hexagonal unit cell, a twisting that results in every Yb ion having exactly one Yb nearest neighbor. Below TN, we found new diffracted intensity due to a k=0 magnetic structure. This magnetic structure was compared to all symmetry-allowed magnetic structures, and was subsequently refined. The best fitting magnetic structure model is antiferromagnetic, and involves pairs of Yb nearest neighbors on which the moments point almost exactly towards each other. This structure has moment components within the ab-plane as well as parallel to the c-axis, although the easy magnetization direction lies in the ab-plane. Our magnetization results suggest that besides the crystal-electric field anisotropy, anisotropic exchange favoring alignment along the c-axis is responsible for the overall direction of the ordered moments. The magnitude of the ordered Yb moments in Yb3Pt4 is 0.81 uB/Yb at 1.4 K. The analysis of the bulk properties, the size of the ordered moment, and the observation of well-defined crystal-field levels argue that the Yb moments are spatially localized in zero field.