Symmetry breaking in covalent chiral bond Hsub2, according to accurate vibrational levels from Kratzer bond theory
G. Van Hooydonk, Y.P. Varshni

TL;DR
This paper demonstrates that Kratzer bond theory accurately predicts vibrational levels of H2, revealing symmetry breaking and chiral behavior in the molecule that are not observable in traditional quantum mechanics.
Contribution
It introduces a novel application of Kratzer bond theory to H2, showing unprecedented accuracy and uncovering symmetry breaking and chiral properties overlooked by quantum mechanics.
Findings
Vibrational levels with errors of 0.00008% using Kratzer theory
Errors smaller than ab initio quantum methods for vibrational quanta
Identification of a Mexican hat potential indicating asymmetry and chirality
Abstract
Symmetry breaking in Hsub2, quantified with Kratzer bond theory, leads to vibrational levels with errors of only 0,00008 %. For quanta, 0,0011 % errors are smaller than with any ab initio QM method. Chiral behavior of covalent bond Hsub2 implies bonding between left- and right-handed atoms HsubL and HsubR or between hydrogen H and antihydrogen Hbar. This generic Hsub2 asymmetry is given away by a Hund-type Mexican hat curve, invisible in QM.
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Taxonomy
TopicsMolecular spectroscopy and chirality · Spectroscopy and Quantum Chemical Studies · Protein Structure and Dynamics
