Multidimensional chemical modelling, II. Irradiated outflow walls
Simon Bruderer (ETH Zurich), Arnold O. Benz (ETH Zurich), Steven D., Doty (Denison University), Ewine F. van Dishoeck (Leiden University, MPE, Garching), Tyler L. Bourke (Harvard-Smithsonian Center for Astrophysics)

TL;DR
This paper presents a 2D chemical model of a high-mass star forming region's outflow walls, explaining CO+ observations by incorporating FUV irradiation effects through outflow cavities, which previous 1D models could not account for.
Contribution
The study introduces the first 2D axi-symmetric chemical model including outflow cavities to explain CO+ abundance in high-mass star forming regions.
Findings
The model reproduces JCMT single-dish observations.
It explains the non-detection by SMA.
CO+ emission originates from FUV-irradiated outflow walls.
Abstract
Observations of the high-mass star forming region AFGL 2591 reveal a large abundance of CO+, a molecule known to be enhanced by far UV (FUV) and X-ray irradiation. In chemical models assuming a spherically symmetric envelope, the volume of gas irradiated by protostellar FUV radiation is very small due to the high extinction by dust. The abundance of CO+ is thus underpredicted by orders of magnitude. In a more realistic model, FUV photons can escape through an outflow region and irradiate gas at the border to the envelope. Thus, we introduce the first 2D axi-symmetric chemical model of the envelope of a high-mass star forming region to explain the CO+ observations as a prototypical FUV tracer. The model assumes an axi-symmetric power-law density structure with a cavity due to the outflow. The local FUV flux is calculated by a Monte Carlo radiative transfer code taking scattering on dust…
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