Simple models for two-dimensional tunable colloidal crystals in rotating ac electric fields

TL;DR

This study compares experimental and simulation results of two-dimensional colloidal crystals formed under rotating ac electric fields, demonstrating tunable lattice spacing influenced by particle size and interaction strengths.

Contribution

It introduces a simple numerical model that accurately predicts the behavior of colloidal crystals under electric fields, highlighting the tunability of lattice spacing.

Findings

Quantitative agreement between experiment and Monte Carlo simulation for moderate interactions.

Lattice spacing can be tuned by external electric fields, with optimal particle size around 1000 nm.

Strong interactions lead to deviations from the model predictions.

Abstract

We compare the behavior of a new two-dimensional aqueous colloidal model system with a simple numerical treatment. To the first order the attractive interaction between the colloids induced by an in-plane rotating ac electric field is dipolar, while the charge stabilization leads to a shorter ranged, Yukawa-like repulsion. In the crystal-like 'rafts' formed at sufficient field strengths, we find quantitative agreement between experiment and Monte Carlo simulation, except in the case of strongly interacting systems, where the well depth of the effective potential exceeds 250 times the thermal energy. The 'lattice constant' of the crystal-like raft is located approximately at the minimum of the effective potential, resulting from the sum of the Yukawa and dipolar interactions.The experimental system has display applications, owing to the possibility of tuning the lattice spacing with the external electric field. Limitations in the applied field strength and relative range of the electrostatic interactions of the particles result in a reduction in tunable lattice spacing for small and large particles, respectively. The optimal particle size for maximizing the lattice spacing tunability was found to be around 1000 nm.