Atmospheric Sulfur Photochemistry on Hot Jupiters

TL;DR

This study develops a 1D photochemical model for hot Jupiter atmospheres, focusing on sulfur species and CO2, revealing their roles in stratospheric heating and metallicity diagnostics.

Contribution

It introduces a new photochemical code that models sulfur chemistry and heating in hot Jupiters, providing insights into sulfur species absorption and CO2 as a metallicity indicator.

Findings

HS absorbs strongly between 300-460 nm, influencing heating.

S2 is less abundant and absorbs at shorter wavelengths.

CO2 mixing ratio correlates with metallicity, unaffected by other parameters.

Abstract

We develop a new 1D photochemical kinetics code to address stratospheric chemistry and stratospheric heating in hot Jupiters. Here we address optically active S-containing species and CO2 at 1200 < T < 2000 K. HS (mercapto) and S2 are highly reactive species that are generated photochemically and thermochemically from H2S with peak abundances between 1-10 mbar. S2 absorbs UV between 240 and 340 nm and is optically thick for metallicities [SH] > 0 at T > 1200 K. HS is probably more important than S2, as it is generally more abundant than S2 under hot Jupiter conditions and it absorbs at somewhat redder wavelengths. We use molecular theory to compute an HS absorption spectrum from sparse available data and find that HS should absorb strongly between 300 and 460 nm, with absorption at the longer wavelengths being temperature sensitive. When the two absorbers are combined, radiative heating (per kg of gas) peaks at 100 microbars, with a total stratospheric heating of about 8 x 10^4 W/m^2 for a jovian planet orbiting a solar-twin at 0.032 AU. Total heating is insensitive to metallicity. The CO2 mixing ratio is a well-behaved quadratic function of metallicity, ranging from 1.6 x 10^-8 to 1.6 x 10^-4 for -0.3 < [M/H] < 1.7. CO2 is insensitive to insolation, vertical mixing, temperature (1200 < T <2000 K), and gravity. The photochemical calculations confirm that CO2 should prove a useful probe of planetary metallicity.